High-Speed High-Resolution Gas-Phase Raman Spectroscopy

Autor: Candace C. Joyner, Sheena T. Patrick, Peter C. Chen, Kanika F. Benton
Rok vydání: 2002
Předmět:
Zdroj: Analytical Chemistry. 74:1618-1623
ISSN: 1520-6882
0003-2700
DOI: 10.1021/ac011129+
Popis: A new Raman spectrometer has been developed that can produce a complete high-resolution gas-phase vibrational spectrum during the time period of a single laser pulse. Conventional gas-phase Raman spectroscopy uses a single narrow-band laser to produce signals that are weak, requiring relatively long collection times. This spectrometer uses a degenerate OPO as a broad-band source that covers a continuous range of >3000 cm-1. When a beam from this broad-band source is added to a narrow-band laser beam, the intensity of the Raman signal is amplified by the nonlinear optical effect. The resulting instrument can generate spectra with high-spectral (
Databáze: OpenAIRE