Triosmium carbonyl cluster derivatives containing pentameric phenyl cyclopolyphosphine

Autor:	Whei-Lu Kwik, How Ghee Ang, Siau Gek Ang, Qi Zhang
Rok vydání:	1995
Předmět:	Inorganic Chemistry chemistry Stereochemistry Ligand Organic Chemistry Materials Chemistry Cluster (physics) chemistry.chemical_element Osmium Crystal structure Physical and Theoretical Chemistry Ring (chemistry) Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 485:C10-C13
ISSN:	0022-328X
DOI:	10.1016/0022-328x(95)91122-z
Popis:	The reactions of the pentaphenylcyclopentaphosphine with [Os 3 (CO) 10 (NCCH 3 ) 2 ] afforded a pair of inversion isomers, ( 1 ) and ( 2 ). [Os 3 (CO) 11 (C 6 H 5 P) 5 ] ( 3 ) and [{Os 3 (CO) 11 } 2 (C 6 H 5 P) 5 ] ( 4 ) were obtained by the treatment of the same ligand with [Os 3 (CO) 11 (NCCH 3 )]. The four new triosmium clusters have been shown by X-ray crystallography to contain an intact cyclopolyphosphine ring in each case.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f10ea97b6d456bcb3c825dacfbbe6944 https://doi.org/10.1016/0022-328x(95)91122-z Zobrazit plný text záznamu