STABILITY OF SALTS OF N-CARBOXY-, N-THIOCARBOXY-, AND N-DITHIOCARBOXYGLYCINE1

Autor:	Arlen W. Frank
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Aqueous solution Chemistry Organic Chemistry Inorganic chemistry Salt (chemistry) Reaction intermediate Nuclear magnetic resonance spectroscopy Carbon-13 NMR Biochemistry Inorganic Chemistry Hydrolysis Polymer chemistry Proton NMR Chemical stability
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 54:109-116
ISSN:	1563-5325 1042-6507
Popis:	Salts of N-carboxy-, N-thiocarboxy-, and N-dithiocarboxyglycine (1–3) have been prepared and their stability in aqueous solution investigated by NMR spectroscopy. Salts of N-carboxyglycine (1) undergo partial hydrolysis in aqueous solution, giving the same equilibrium mixtures as those formed in the reaction of glycine with carbonate. Salts of N-dithiocarboxyglycine (2) are stable in aqueous solution. even at 100°C. The disodium salt 2d, which has often been employed as a reaction intermediate but never adequately characterized, has been synthesized by several independent methods. Salts of N-thiocarboxyglycine (3) are stable in aqueous solution at 25°C but not at 100°C.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f1055a7f40cabbf517d1cb5ee9595b63 https://doi.org/10.1080/10426509008042127 Zobrazit plný text záznamu