Selective Synthesis of Methanol from CO + H2over Pd Sulfide in the Presence of H2S

Autor:	Akihiro Miyazawa, Muneyoshi Yamada, Takuro Furukawa, Naoto Koizumi
Rok vydání:	2001
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Sulfide Chemistry Inorganic chemistry General Chemistry Methanol Syngas
Zdroj:	Chemistry Letters. 30:1282-1283
ISSN:	1348-0715 0366-7022
Popis:	Both bulk and SiO2-supported Pd sulfides were found to show methanol synthesis activity from CO + H2 (syngas). SiO2-supported Pd sulfide yielded 120 g kg-cat−1 h−1 of methanol at 613 K, 5.1 Mpa and 20 m3 (STP) kg-cat−1 h−1. In the presence of H2S 120 ppm in concentration, it preserved 40% of the activity that was obtained under the sulfur-free conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f0fa58ccbeb6f0cdc2e2097540267ba9 https://doi.org/10.1246/cl.2001.1282 Zobrazit plný text záznamu