A new reaction of acetylenes with terminal ternary bonds
Autor: | I. L. Kotlyarevskii, Mark S. Shvartsberg, A. N. Kozhevnikova, V. N. Andrievskii |
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Rok vydání: | 1970 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 19:1079-1082 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf01084322 |
Popis: | 1. The authors have developed a new method of direct introduction of acetylene substituents into aromatic and heteroaromatic rings, consisting in single stage condensation of acetylene with terminal triple bonds with aryl and hetaryl halides in the presence of bases and metallic copper. 2. The use of acetals of tertiary acetylene alcohols in condensation is a method of obtaining monosubsituted aryl and hetaryl acetylenes. |
Databáze: | OpenAIRE |
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