The stereochemical requirement in the fragmentation of 9-bromocamphor derivatives. A new class of chiral pool elements containing asymmetric quaternary carbon centers

Autor:	Uma N. Sundram, Kim F. Albizati
Rok vydání:	1991
Předmět:	Bicyclic molecule Fragmentation (mass spectrometry) Chemistry Stereochemistry Organic Chemistry Leaving group Bond cleavage Quaternary carbon
Zdroj:	The Journal of Organic Chemistry. 56:2622-2624
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00008a010
Popis:	The fragmentation of 9-bromobornan-2-ol derivatives is dependent on both the orientation and identity of the leaving group at the 2-position. This has led to a synthesis of compounds containing useful quaternary carbon centers in carbocyclic six-membered rings, a previously unknown type of chiral pool elements
Databáze:	OpenAIRE
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