Phase equilibria in Al-Ni-Zr system at 1123 K
Autor: | K. B. Kalmykov, S. F. Dunaev, D. M. Kondrat’ev, N. E. Dmitrieva |
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Rok vydání: | 2012 |
Předmět: | |
Zdroj: | Moscow University Chemistry Bulletin. 67:259-264 |
ISSN: | 1935-0260 0027-1314 |
DOI: | 10.3103/s0027131412060053 |
Popis: | Phase equilibria in ternary Al-Ni-Zr system have been studied using X-ray phase and electron probe microanalyses at 1123 K in the content range of 0–45 at % Al. A fragment of the isothermal section of this system has been plotted. The existence of three-phase equilibria Zr7Ni10 + Zr8Ni21 + Zr2Ni7, τ2-ZrNi2Al + NiAl + Zr2Ni7, NiAl + Ni3Al + Zr2Ni7, Zr7Ni10 + Zr2Ni7 + τ2-ZrNi2Al at 1123 K has been established for the first time. Phase based of binary compound Zr2Ni7 dissolves up to 13 at % aluminum. The crystalline structure of the τ7-Zr5Ni4Al phase has been determined, including structure type U3Si2, spatial group P4/mbm (a = 7.1852(7) A, c = 3.3019(5) A). |
Databáze: | OpenAIRE |
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