ChemInform Abstract: Graphitic Carbon Nitride Polymer as a Recyclable Photoredox Catalyst for Fluoroalkylation of Arenes

Autor:	Siegfried Blechert, Moritz Baar
Rok vydání:	2015
Předmět:	Sulfonyl chemistry.chemical_classification chemistry.chemical_compound chemistry Chemical engineering Graphitic carbon nitride Water splitting General Medicine Polymer Heterogeneous catalysis Mesoporous material Visible spectrum Catalysis
Zdroj:	ChemInform. 46
ISSN:	0931-7597
DOI:	10.1002/chin.201522060
Popis:	Heterogeneous catalysis for trifluoromethylations and perfluoroalkylations has been performed. Through the usage of cheap, metal-free and recyclable mesoporous graphitic carbon nitride (mpg-CN) it was possible to fluoroalkylate various arenes by the reductive activation of sulfonyl chlorides with visible light. Thus, we were able to demonstrate the robustness and versatility of mpg-CN as a photoredox catalyst beyond water splitting and the activation of oxygen.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f094d03196f3c6e02c0650ad0b2bb762 https://doi.org/10.1002/chin.201522060 Zobrazit plný text záznamu Plný text