Second and third virial coefficients for polyisobutylene in cyclohexane

Autor:	Takashi Norisuye, Yo Nakamura, Ken-ichi Katayama, Akio Teramoto, Kazutomo Akasaka
Rok vydání:	1992
Předmět:	Polymers and Plastics Cyclohexane Intrinsic viscosity Organic Chemistry Thermodynamics Radius Light scattering Inorganic Chemistry chemistry.chemical_compound chemistry Virial coefficient Materials Chemistry Radius of gyration Polystyrene Benzene
Zdroj:	Macromolecules. 25:1134-1138
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma00029a020
Popis:	The molecular weight dependence of the second and third virial coefficients, the z-average radius of gyration and the zero-shear intrinsic viscosity was studied using light scattering. For M w higher than 7x10 4 A 3 and z vary as M w 0.6 and M w 1.19 , respectively and the factor g defined by A 3 /A 2 M w increases with increasing M w . The interpenetration function Ψ anf g plotted against the cube of the radius expansion factor are almost superimposed on the respective relations for polystyrene in benzene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f0897a97319cf7147a237069b4ca037c https://doi.org/10.1021/ma00029a020 Zobrazit plný text záznamu