ChemInform Abstract: Monohydroxylation of Cyclic and Acyclic β-Keto Esters with Molecular Oxygen Catalyzed by Cobalt(II) Chloride in Neutral Conditions

Autor: Sylvain Jugé, Jacques Uziel, Xavier Baucherel, Eric Levoirier
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 31
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200020062
Popis: Cyclic and acyclic α-alkyl-α-hydroxy-β-keto esters 2 were obtained with 50–100% isolated yields from the corresponding β-keto esters 1 by oxidation with molecular oxygen in a mixture of CH 3 CN/ i -PrOH and in the presence of cobalt(II) chloride.
Databáze: OpenAIRE