ChemInform Abstract: Monohydroxylation of Cyclic and Acyclic β-Keto Esters with Molecular Oxygen Catalyzed by Cobalt(II) Chloride in Neutral Conditions
Autor: | Sylvain Jugé, Jacques Uziel, Xavier Baucherel, Eric Levoirier |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 31 |
ISSN: | 1522-2667 0931-7597 |
DOI: | 10.1002/chin.200020062 |
Popis: | Cyclic and acyclic α-alkyl-α-hydroxy-β-keto esters 2 were obtained with 50–100% isolated yields from the corresponding β-keto esters 1 by oxidation with molecular oxygen in a mixture of CH 3 CN/ i -PrOH and in the presence of cobalt(II) chloride. |
Databáze: | OpenAIRE |
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