Hypophosphite complexes of the lanthanide metals, [Ln(H2PO2)x(OH)3−x(H2O)n] (Ln = LaNd, Sm, Eu, DyEr, Yb, Lu)

Autor: Joanne A. Seddon, Andrew W.G. Platt, Roman A. Kresinski, Andrew Jackson
Rok vydání: 1996
Předmět:
Zdroj: Polyhedron. 15:1899-1902
ISSN: 0277-5387
DOI: 10.1016/0277-5387(95)00564-1
Popis: Reactions between Ln(No3)3 and NaH2PO2 afforded a series of complexes [Ln(H2PO2)x(OH)3−x(H2O)n] (Ln = LaNd, Sm, Eu, Sm, Eu, DyEr, Yb, Lu). This series possesses members falling into at least five separate structural types, three of which are here reported for the first time. The crystal structure of [Pr(H2PO2)3], a member of one of the new structural types, is reported.
Databáze: OpenAIRE