Hypophosphite complexes of the lanthanide metals, [Ln(H2PO2)x(OH)3−x(H2O)n] (Ln = LaNd, Sm, Eu, DyEr, Yb, Lu)
Autor: | Joanne A. Seddon, Andrew W.G. Platt, Roman A. Kresinski, Andrew Jackson |
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Rok vydání: | 1996 |
Předmět: | |
Zdroj: | Polyhedron. 15:1899-1902 |
ISSN: | 0277-5387 |
DOI: | 10.1016/0277-5387(95)00564-1 |
Popis: | Reactions between Ln(No3)3 and NaH2PO2 afforded a series of complexes [Ln(H2PO2)x(OH)3−x(H2O)n] (Ln = LaNd, Sm, Eu, Sm, Eu, DyEr, Yb, Lu). This series possesses members falling into at least five separate structural types, three of which are here reported for the first time. The crystal structure of [Pr(H2PO2)3], a member of one of the new structural types, is reported. |
Databáze: | OpenAIRE |
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