Formation of halogenotricarbonyl(N,N′-dimethylethane-1,2-diamine)rheniums; and the crystal and molecular structure of bromotricarbonyl(N,N′,dimethylethane-1,2-diamine)rhenium(I)

Autor:	Edward W. Abel, Mohamed A. Mazid, Maqbool M. Bhatti, Michael B. Hursthouse, K. M. Abdul Malik
Rok vydání:	1980
Předmět:	Ligand Organic Chemistry Inorganic chemistry chemistry.chemical_element Bromine atom Rhenium Biochemistry Nitrogen Inorganic Chemistry Crystal chemistry.chemical_compound chemistry Diamine Polymer chemistry Materials Chemistry Molecule Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 197:345-355
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)84688-4
Popis:	The complexes [ReX(CO)3{Me(H)NCH2CH2N(H)Me}], (X = Cl, Br and I) have been prepared and characterised. The molecular structure of the bromotricarbonyl(N,N′-dimethylethane-1,2-diamine)rhenium(I) has been shown to have the bromine atom cis to both donor nitrogen atoms, and each of the methyl groups of the dmen ligand is positioned away from the bromine atom.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f05fd03304f764e1eeb6de7333fec221 https://doi.org/10.1016/s0022-328x(00)84688-4 Zobrazit plný text záznamu