Synthesis of Rh6(CO)16 in Supercages of Zeolite HY: Reaction Network and Kinetics of Formation from Mononuclear Rhodium Precursors via Rh4(CO)12 Facilitated by the Water Gas Shift Half-Reaction

Autor:	Bruce C. Gates, Cong Yan Chen, Chia Yu Fang, Edward T. Conley, Pedro Castaño, José Valecillos
Rok vydání:	2019
Předmět:	General Energy Half-reaction Chemistry Kinetics chemistry.chemical_element Physical and Theoretical Chemistry Zeolite Photochemistry Water-gas shift reaction Surfaces Coatings and Films Electronic Optical and Magnetic Materials Rhodium
Zdroj:	The Journal of Physical Chemistry C. 124:2513-2520
ISSN:	1932-7455 1932-7447
DOI:	10.1021/acs.jpcc.9b10291
Popis:	Rh(I)(CO)2 complexes anchored to zeolite HY were converted into Rh4(CO)12 in the zeolite supercages upon exposure to flowing CO + H2O at 35 °C, and the chemistry and kinetics were characterized wit...
Databáze:	OpenAIRE
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