THE SYNTHESIS AND CHARACTERIZATION OF COPPER(II) AND NICKEL(II) COMPLEXES OF NOVEL 16-MEMBERED MACROCYCLIC LIGANDS HAVING VARYING DEGREES OF SATURATION

Autor:	Arthur E. Martell, John W. L. Martin, James H. Timmons
Rok vydání:	1980
Předmět:	chemistry.chemical_classification Diene Double bond Inorganic chemistry chemistry.chemical_element Copper Metal chemistry.chemical_compound Nickel chemistry visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Saturation (chemistry)
Zdroj:	Journal of Coordination Chemistry. 10:251-255
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958978008079871
Popis:	Novel tetraaza[16] diene macrocyclic complexes of nickel(II) and copper(II) have been synthesized by the reaction of 4,4,9,9-tetramethyl-5,8-diazadodeca-2,11-dione with 1,4-butanediamine in the presence of the corresponding metal ion. The C[sbnd]N double bonds of the macrocycle have been hydrogenated using NaBH4 for both the nickel(II) and copper(II) complexes. The preparation and properties of a series of complexes of macrocycles having a varying degree of saturation are described.
Databáze:	OpenAIRE
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