Atmospheric Fate of Chlorobromomethane: Rate Constant for the Reaction with OH, UV Spectrum, and Water Solubility

Autor:	Robert E. Huie, Michael J. Kurylo, A G. Guschin, Vladimir L. Orkin, Victor G. Khamaganov
Rok vydání:	1997
Předmět:	Arrhenius equation Aqueous solution Chemistry Analytical chemistry Atmospheric temperature range law.invention symbols.namesake Reaction rate constant Resonance fluorescence law symbols Flash photolysis Physical and Theoretical Chemistry Solubility Electron paramagnetic resonance
Zdroj:	The Journal of Physical Chemistry A. 101:174-178
ISSN:	1520-5215 1089-5639
Popis:	The rate constant for the reaction of CH2ClBr with OH was measured by both flash photolysis resonance fluorescence and discharge flow electron paramagnetic resonance techniques over the temperature range 277−370 K. The Arrhenius expression × 10-12 exp{−(978 ± 72)/T} cm3 molecule-1 s-1 was derived from a composite fit to both data sets. Absorption cross-sections of CH2ClBr were measured from 187 to 290 nm at 295 K. The solubility of CH2ClBr in water was also estimated to determine if such a process could be important in determining the atmospheric lifetime of CH2ClBr. The atmospheric lifetime and ozone depletion potential for CH2ClBr were estimated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f03692491bee7b318c295c51848cdd01 https://doi.org/10.1021/jp962428j Zobrazit plný text záznamu