Lead Carbodiimides Related to the Mineral Bideauxite

Autor:	Konstantin Dolabdjian, Hans-Jürgen Meyer
Rok vydání:	2017
Předmět:	Chemistry Intercalation (chemistry) Inorganic chemistry 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Chloride 0104 chemical sciences Inorganic Chemistry Metal Crystallography chemistry.chemical_compound Bromide visual_art medicine visual_art.visual_art_medium Salt metathesis reaction Cyanamide 0210 nano-technology medicine.drug Carbodiimide
Zdroj:	Zeitschrift für anorganische und allgemeine Chemie. 643:1898-1903
ISSN:	1521-3749 0044-2313
DOI:	10.1002/zaac.201700201
Popis:	Solid state metathesis reactions of PbCl2 with metal carbodiimides yielded multinary lead carbodiimide chlorides APb2Cl3(CN2) (A = Li, Na, Ag). Their crystal structures strongly relate to the mineral Bideauxite [AgPb2Cl3(OH,F)2], all crystallizing in the space group Fd3m. The same crystal structure exists not only with chloride but also with bromide. Another compound obtained in this system is LiPbCl(CN2) with a crystal structure that can be considered as the result of an intercalation of LiCl into the layered structure of Pb(CN2).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f030c0d87b0a970393f5481330331006 https://doi.org/10.1002/zaac.201700201 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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