Reduction of α,β-unsaturated nitroalkenes with borane and borohydrides. A convenient route to 3-nitro-, 3-hydroxylamino-, and 3-amino-2h-1-benzopyran derivatives

Autor: George W. Kabalka, Rajender S. Varma, Y.-Z. Gai
Rok vydání: 1987
Předmět:
Zdroj: Journal of Heterocyclic Chemistry. 24:767-772
ISSN: 1943-5193
0022-152X
Popis: The borohydride catalyzed borane reduction of 3-nitrochromenes provided a facile route to a variety of 3-hydroxylamino- 5 and 3-amino-2H-1-benzopyranes 6. Reduction with methoxyborohydride species, on the other hand, provided 3-nitrochromans 2,4.
Databáze: OpenAIRE