| Autor: |
Gottfried Huttner, Laszlo Zsolnai, Horst Heidel, Johannes Scherer, Olaf Walter, A. Asam |
| Rok vydání: |
1995 |
| Předmět: |
|
| Zdroj: |
Chemische Berichte. 128:293-301 |
| ISSN: |
0009-2940 |
| DOI: |
10.1002/cber.19951280314 |
| Popis: |
Fe(NCMe) Complexes of Chiral Tripod Ligands Bearing three Different Donor Groups: Dynamics and Structure Chiral tripod ligands [tripod = CH3C(CH2PR2)(CH2PR′2)(CH2-PR′′2), 1a–d] with three different donor groups react with Fe(NCMe)6(BF4)2 to yield the complexes tripodFe(NCMe)3(BF4)2 (2a–d). These complexes show an idealized octahedral coordination based on a facial coordination of the tripod ligand. The asymmetry of the chiral tripod ligands a–d induces a differentiation of the remaining coordination sites at iron. The structure and the dynamic behaviour of the compounds 2a, b is elucidated by X-ray structural analyses and 2D-NMR techniques. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
Plný text