Zwitterionic quaternary ammonium alkoxides: organic strong bases

Autor:	Eva G. Lovett
Rok vydání:	1991
Předmět:	chemistry.chemical_compound Organic base chemistry Tertiary amine Organic Chemistry Alkoxide Polymer chemistry Glycidol Hofmann elimination Disproportionation Ammonium Aliphatic compound
Zdroj:	The Journal of Organic Chemistry. 56:2755-2758
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00008a034
Popis:	Stable quaternary ammonium alkoxides, a new type of organic strong base, were obtained from unhindered tertiary alkanolamines and glycidol. At elevated temperatures, the 2-hydroxyethyl derivatives underwent intramolecular rearrangements and deoxyalkylation to form tertiary amine terminated 1,4-poly(3-hydroxyoxetanes). Demethylation was also observed. The 3-hydroxypropyl derivative underwent disproportionation and Hofmann elimination in addition
Databáze:	OpenAIRE
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