Facile preparation of polycarbonates from bio-based eugenol and 2-methoxy-4-vinylphenol

Autor:	Bai De, Caijuan Huang, Michael North, Qin Chen, Tianhua Ren, Haibo Xie, Changbo Zhao, Mengqian Huang
Rok vydání:	2020
Předmět:	Polymers and Plastics Molecular mass Organic Chemistry Bio based Bioengineering Biochemistry Eugenol chemistry.chemical_compound Monomer 2-Methoxy-4-vinylphenol chemistry Thioether Click chemistry Carbonate Organic chemistry
Zdroj:	Polymer Chemistry. 11:5133-5139
ISSN:	1759-9962 1759-9954
DOI:	10.1039/d0py00291g
Popis:	Two α,ω-diene monomers containing a carbonate structure derived from eugenol and 2-methoxy-4-vinylphenol were successfully synthesized in high yields of 94% and 78%, respectively. With these dienes in hand, a series of poly(thioether carbonates) and unsaturated aromatic–aliphatic polycarbonates with moderate molecular weights (Mn) ranging from 17 100 to 24 400 g mol−1 and tunable thermo-properties were prepared via a thiol–ene click reaction and step growth acyclic-diene-metathesis, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f0110b6bc7e9c023bf0b764c2af866f5 https://doi.org/10.1039/d0py00291g Zobrazit plný text záznamu