Glycidyl esters. III. Reaction of diglycidyl esters and cyclic carboxylic anhydrides

Autor:	G. Maerker, H. A. Monroe, W. S. Port
Rok vydání:	1963
Předmět:	Materials science Polymers and Plastics Gel time Succinic anhydride Maleic anhydride General Chemistry Hexahydrophthalic anhydride Surfaces Coatings and Films chemistry.chemical_compound Chain length Monomer chemistry Polymer chemistry Materials Chemistry Organic chemistry Reactivity (chemistry)
Zdroj:	Journal of Applied Polymer Science. 7:301-307
ISSN:	1097-4628 0021-8995
DOI:	10.1002/app.1963.070070127
Popis:	The diglycidyl esters of oxalic, succinic, adipic, pimelic, azelaic, and sebacic acids were prepared and were made to react with o-phthalic anhydride to form crosslinked resins. The chain length of the monomeric diglycidyl esters was found to be directly related to the gel time and inversely related to the heat distortion temperatures of the derived resins, although neither relationship was linear. The reaction of diglycidyl sebacate and of diglycidyl azelate with several cyclic carboxylic anhydrides showed the reactivity of the anhydrides toward the esters to decrease in the following order: tetrahydrophthalic anhydride > maleic anhydride > hexahydrophthalic anhydride > succinic anhydride > nadic methyl anhydride.
Databáze:	OpenAIRE
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