Reaction Kinetics Based Optimization of Furfural Production from Corncob Using a Fully Recyclable Solid Acid
| Autor: | Xinnian Zhang, Hairui Ji, Liheng Chen, Roland Gleisner, Junyong Zhu |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
integumentary system
010405 organic chemistry Chemistry General Chemical Engineering General Chemistry Solid acid Corncob 010402 general chemistry Furfural 01 natural sciences Industrial and Manufacturing Engineering 0104 chemical sciences Catalysis Chemical kinetics chemistry.chemical_compound Hydrolysis Yield (chemistry) Degradation (geology) Organic chemistry |
| Zdroj: | Industrial & Engineering Chemistry Research. 55:11253-11259 |
| ISSN: | 1520-5045 0888-5885 |
| Popis: | To achieve green processing through recycling catalysts, this study demonstrated a commercial solid acid toluenesulfonic acid (p-TsOH) for furfural production from corncob. Acid recyclability study indicate that crystalized p-TsOH was highly effective for furfural production. A kinetic based reaction severity, combined hydrolysis factor (CHF), was used to develop a furfural predictive model with the consideration of loss through degradation. Furfural yield of approximately 75% theoretical was achieved in a CHF range between 830 and 1850. |
| Databáze: | OpenAIRE |
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