X-Ray Structural Analysis of a Novel Lithium Hydride/Lithiumtert-Butoxide Superaggregate: Li33H17(OtBu)16

Autor:	Richard J. Lagow, Thomas Kottke, Ruthanne D. Thomas, Daniele Hoffmann
Rok vydání:	1998
Předmět:	chemistry.chemical_compound Crystallography chemistry Lithium hydride Inorganic chemistry X-ray General Chemistry Solubility Catalysis
Zdroj:	Angewandte Chemie International Edition. 37:1537-1539
ISSN:	1521-3773 1433-7851
Popis:	Extraordinary solubility in hydrocarbons is exhibited by the novel superaggregate Li33 H17 (OtBu)16 , which crystallizes from photolyzed solutions of lithium tert-butoxide and tert-butyllithium (ROLi:RLi≥7:3). The structure of the compound (the framework of Li, H, and O atoms without tBu groups is shown on the right) resembles a disrupted lithium hydride lattice with an inner hydride-rich core and an outer shell of lipophilic tert-butoxide groups.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f00b2e3a1c100366b5eca40bdee5a81a https://doi.org/10.1002/(sici)1521-3773(19980619)37:11<1537::aid-anie1537>3.0.co Zobrazit plný text záznamu Plný text