X-Ray Structural Analysis of a Novel Lithium Hydride/Lithiumtert-Butoxide Superaggregate: Li33H17(OtBu)16
Autor: | Richard J. Lagow, Thomas Kottke, Ruthanne D. Thomas, Daniele Hoffmann |
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Rok vydání: | 1998 |
Předmět: | |
Zdroj: | Angewandte Chemie International Edition. 37:1537-1539 |
ISSN: | 1521-3773 1433-7851 |
Popis: | Extraordinary solubility in hydrocarbons is exhibited by the novel superaggregate Li33 H17 (OtBu)16 , which crystallizes from photolyzed solutions of lithium tert-butoxide and tert-butyllithium (ROLi:RLi≥7:3). The structure of the compound (the framework of Li, H, and O atoms without tBu groups is shown on the right) resembles a disrupted lithium hydride lattice with an inner hydride-rich core and an outer shell of lipophilic tert-butoxide groups. |
Databáze: | OpenAIRE |
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