Functionalization of graphene oxide with naphthalenediimide diamine for high-performance cathode materials of lithium-ion batteries
| Autor: | Yuanrui Gao, Yanyong Sha, Hanping Zhang, Hongjiang Liu, Hao Wen, Hongren Rong, Qi Liu, Yidan Song |
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| Rok vydání: | 2018 |
| Předmět: |
Materials science
Scanning electron microscope Oxide Energy Engineering and Power Technology chemistry.chemical_element 02 engineering and technology 010402 general chemistry 01 natural sciences law.invention chemistry.chemical_compound symbols.namesake X-ray photoelectron spectroscopy law Fourier transform infrared spectroscopy Renewable Energy Sustainability and the Environment Graphene 021001 nanoscience & nanotechnology Cathode 0104 chemical sciences Fuel Technology chemistry Chemical engineering symbols Lithium 0210 nano-technology Raman spectroscopy |
| Zdroj: | Sustainable Energy & Fuels. 2:803-810 |
| ISSN: | 2398-4902 |
| DOI: | 10.1039/c7se00543a |
| Popis: | Through the covalent bonding between naphthalenediimide diamine (NDIDA) and graphene oxide (GO), we synthesize NDIDA-functionalized graphene oxide (NDIDA-GO). The as-synthesized NDIDA-GO is characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, Raman spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, and the Brunauer–Emmett–Teller surface area analysis. As a cathode material for lithium-ion batteries, within a voltage window of 4.5–1.5 V, NDIDA-GO exhibits a high specific capacity, good cyclic stability, and rate capability, keeping a specific capacity of 240 mA h g−1 after 50 cycles at 50 mA g−1. This work provides an effective route for the development of high-performance organic-based cathode materials for lithium-ion batteries. |
| Databáze: | OpenAIRE |
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