Electron-transfer kinetics of the iron (II)-vanadium (V), iron (III)-vanadium (IV) system in aqueous perchlorate, by platinum-electrode polarography

Autor:	D. R. Rosseinsky, Michael J. Nicol
Rok vydání:	1966
Předmět:	Polarography Aqueous solution Proton General Chemical Engineering Inorganic chemistry Vanadium chemistry.chemical_element Reversible reaction Electron transfer Perchlorate chemistry.chemical_compound chemistry Electrochemistry Platinum
Zdroj:	Electrochimica Acta. 11:1069-1077
ISSN:	0013-4686
DOI:	10.1016/0013-4686(66)80044-0
Popis:	Separate measurements of forward and reverse reaction rates of the reaction Fe(II)+V(V)⇄Fe(III)+V(IV)Fe(II)+V(V)⇄Fe(III)+V(IV) have been obtained at several temperatures by measurements of the Fe(II) diffusion current. These confirm that the major paths have rate terms respectively proportional to and inversely proportional to [H +], although medium effects are also apparent. An interpretation of the very low ΔH1* (1·69 Kcal/mole) for the major foward path is given in terms of a proton transfer coefficient.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::efc2ecfc3d81b336ac82a42e9c642605 https://doi.org/10.1016/0013-4686(66)80044-0 Zobrazit plný text záznamu