| Autor: |
V. Nataraju, E. Ravisankar, S.K. Gupta, Varun K. Yadav, Vilas M. Mahadeshwar, T.K. Saha, M.M. Gulhane, R.K. Bhatia |
| Rok vydání: |
2013 |
| Předmět: |
|
| Zdroj: |
International Journal of Mass Spectrometry. :39-44 |
| ISSN: |
1387-3806 |
| DOI: |
10.1016/j.ijms.2013.02.008 |
| Popis: |
Aperture of collectors in multiple Faraday Collector system is limited to typically 1 mm due to limited dispersion of ion beams of different masses and this in turn makes it difficult to achieve required peak flatness on all collectors. Further, for analysis of different elements, positions of collectors need to be mechanically adjusted from outside the vacuum system and this makes the collector system very unwieldy. To circumvent these problems, a new collector system based on variable dispersion zoom optics has been developed that facilitates fixed collector cups with wider apertures. The collector position adjustability is replaced by the variability of the dispersion using a DC quadrupole followed by deflection optics that provides matched peaks with increased peak flatness for different elements. Advantage of new optics has been demonstrated by 87 Sr/ 86 Sr isotopic ratio measurement whereby precision has been improved to 8 ppm compared to 23 ppm obtained with the conventional collector setup on the same instrument. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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Full Text from ScienceDirect