Solid state structures of [hydrotris(3-tert-butyl-5-methylpyrazolyl)borato]chlorotin and -cadmium. Stereochemical influence of a central atom lone pair

Autor:	Josef Takats, Arnold L. Rheingold, Brian S. Haggerty, Scott S. Mason, Daniel L. Reger, Xing Wang Zhang
Rok vydání:	1993
Předmět:	Ionic radius Chemistry Stereochemistry Ligand chemistry.chemical_element Crystal structure Ring (chemistry) Inorganic Chemistry Trigonal bipyramidal molecular geometry Crystallography Molecule Physical and Theoretical Chemistry Tin Lone pair
Zdroj:	Inorganic Chemistry. 32:4345-4348
ISSN:	1520-510X 0020-1669
Popis:	The complexes [HB(3-Bu t -5-Mepz) 3 ] SnCl and [HB(3-Bu t pz) 3 ]CdCl(pz=pyrazolyl ring) have been prepared and their solid-state structures determined ciystallographically. The two structures allow a determination of the impact of the lone pair on ligand geometry and on the metal-donor atom distances for two metals with equivalent ionic radii. The geometry about tin in [HB(3-Bu t -5-Mepz) 3 ] SnCl is best described as a distorted trigonal bipyramid with the chloride ligand in an axial site and the tin lone pair occupying an equatorial position
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::efb853b0c08b1189db141e95aa5b26f3 https://doi.org/10.1021/ic00072a030 Zobrazit plný text záznamu