Molecular and Crystal Structure of B6H10

Autor:	E. L. Lippert, Richard E. Dickerson, William N. Lipscomb, F. L. Hirshfeld, K. Eriks
Rok vydání:	1958
Předmět:	Hydrogen Plane (geometry) General Physics and Astronomy chemistry.chemical_element Crystal structure Crystallography chemistry X-ray crystallography Physics::Atomic and Molecular Clusters Perpendicular Molecular symmetry Molecule Physical and Theoretical Chemistry Boron
Zdroj:	The Journal of Chemical Physics. 28:56-61
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.1744080
Popis:	The approximately pentagonal pyamidal arrangement for boron atoms in B6H10 has been shown to be attached to a hydrogen arrangement resulting in Cs‐m molecular symmetry. There are four bridge hydrogens and no BH2 groups in the molecule. The boron framework is bonded, to a very rough approximation, by two electron‐pair bonds and two three‐center bonds. The electron‐pair bond perpendicular to the molecular symmetry plane is usually short (1.60 A). Comparison with other boron hydrides leads to some tentative conclusions about factors governing the relative stabilities of these compounds.
Databáze:	OpenAIRE
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