A microwave-optical double resonance spectroscopic study of TiO and TiN
| Autor: | Jeffrey E. Shirley, L. R. Russon, K. Y. Jung, C. T. Scurlock, Timothy C. Steimle |
|---|---|
| Rok vydání: | 1990 |
| Předmět: |
chemistry.chemical_classification
Materials science Analytical chemistry Resonance Rotational transition chemistry.chemical_element Atomic and Molecular Physics and Optics Condensed Matter::Materials Science Nuclear magnetic resonance chemistry Rotational spectroscopy Physical and Theoretical Chemistry Ground state Spectroscopy Tin Hyperfine structure Inorganic compound |
| Zdroj: | Journal of Molecular Spectroscopy. 144:27-31 |
| ISSN: | 0022-2852 |
| DOI: | 10.1016/0022-2852(90)90305-a |
| Popis: | The J = 2 ← J = 1 and J = 3 ← J = 2 pure rotational transitions of TiO ( X 3 Δ) and the N = 2 ← N = 1 pure rotational transition of TiN ( X 2 Σ + ) have been recorded using the technique of microwave-optical double resonance (MODR) spectroscopy. There was no evidence of Λ-doubling in the spectra of TiO and no evidence of hyperfine splitting in the spectra of TiN. An improved set of spectroscopic parameters for the ground state of these two molecules is given and are used to predict the pure rotational transition frequencies associated with low-lying rotational levels. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|