Quantum-chemical investigation of deoxypeganine and its salts I. Photochemical oxidation of deoxypeganine

Autor:	Kh. R. Nuriddinov, K. D. Sargazakov, L. V. Molchanov, Kh. N. Aripov, M. A. Ashirmatov
Rok vydání:	1992
Předmět:	Solvent Quantum chemical Molecular interactions Chemistry Linear combination of atomic orbitals Computational chemistry Excited state Molecule Plant Science General Chemistry Physics::Chemical Physics Photochemistry General Biochemistry Genetics and Molecular Biology
Zdroj:	Chemistry of Natural Compounds. 28:477-479
ISSN:	1573-8388 0009-3130
DOI:	10.1007/bf00630656
Popis:	Hypothetical models of the interaction of deoxypeganine molecules with a solvent have been considered by the MO LCAO quantum-chemical method in the AM1 approximation. Excited triplet states of deoxypeganine and its analogues have been calculated by the method of molecular interactions. A free-radical mechanism of photochemical oxidation has been proposed on the basis of the results obtained and of literature information.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ef78832e94a06b28dde4fa0eed1fdac2 https://doi.org/10.1007/bf00630656 Zobrazit plný text záznamu Full text from SpringerLink