Arene–Arene Stacking incis-Bis[2-(2-thienyl-C3)pyridine-N]platinum(II)
| Autor: | Klaus-Jürgen Range, A. Von Zelewsky, Hartmut Yersin, Josef Breu |
|---|---|
| Rok vydání: | 1997 |
| Předmět: |
Stereochemistry
Stacking chemistry.chemical_element General Medicine Crystal structure Electrostatics General Biochemistry Genetics and Molecular Biology Metal Crystallography chemistry.chemical_compound chemistry visual_art Pyridine visual_art.visual_art_medium Molecule Platinum Multipole expansion |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 53:562-565 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270196015053 |
| Popis: | In the crystal structure of the title complex, [Pt(C9H6NS)2], although the aromatic ligands are coordinated to a central heavy metal atom, T-shaped and shifted π-stacked arrangements of the aromatic moieties are preferred, leading to a sandwich herring-bone type of crystal-packing motif. The crystal structure is therefore consistent with the view that the arene–arene interactions are determined by electrostatics (multipole–multipole). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text