Kinetics of pi-complex isomerization during AlCl3 -catalyzed Friedel-Crafts reactions between linear olefins and p-xylene

Autor:	Jeffrey C. Gee, Samuel J. Gee, Lauren M. Kattchee
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Double bond Organic Chemistry Kinetics Aromaticity Photochemistry Medicinal chemistry p-Xylene Catalysis chemistry.chemical_compound chemistry Physical and Theoretical Chemistry Friedel–Crafts reaction Isomerization Alkyl
Zdroj:	Journal of Physical Organic Chemistry. 27:583-588
ISSN:	0894-3230
Popis:	Rapid isomerization of pi-complex intermediates results in the formation of multiple isomers of alkyl aromatics during AlCl3-catalyzed reactions between linear olefins and aromatic rings. The authors present results of a kinetic study of reactions between p-xylene, 1-dodecene, and linear tetradecenes. Product distributions are well predicted based on a model of reversible pi-complex isomerization. Surprisingly, no double bond isomerization was observed in the linear olefins: All isomerization occurred in the pi-complexes. Copyright © 2014 John Wiley & Sons, Ltd.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ef5f883dce04034e55e5c36e7429be9d https://doi.org/10.1002/poc.3303 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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