Molecular Sensing and Color Manipulation Based on Dimension-Controlled Plasmon-Enhanced Silicon Nanotube SERS Substrates
| Autor: | Li-Wei Nien, Hsin-Chia Ho, Yi-Chen Lai, Jia-Han Li, Chun-Hway Hsueh |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Silicon nanotube
Materials science business.industry Scattering 02 engineering and technology Substrate (electronics) 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials symbols.namesake General Energy Electric field symbols Optoelectronics Physical and Theoretical Chemistry 0210 nano-technology business Raman spectroscopy Nanoring Excitation Plasmon |
| Zdroj: | The Journal of Physical Chemistry C. 122:8510-8516 |
| ISSN: | 1932-7455 1932-7447 |
| DOI: | 10.1021/acs.jpcc.8b00376 |
| Popis: | The system of suspended gold nanoring on silicon nanotube substrate with enhanced light harvesting and electromagnetic field enhancements was proposed in the present study. The effects of outer/inner diameter (D/d) ratio of the ring and tube on the plasmonic behavior were studied by systemic simulations and experiments. In simulations, the high order quadrupole–dipole mode was also excited in addition to the typical dipole–dipole mode, and the resonant configurations were characterized by both electric field profile and resonant surface charge distribution. Experimentally, both dark-field and Raman microscopies were conducted to examine the plasmonic behavior. The plasmon-enhanced scattering could be controlled by tailoring the D/d ratio, and the dark-field image colors could be manipulated covering the visible range. Raman spectra using two excitation wavelengths were also recorded and showed good agreement with calculated enhancement factor which, in turn, provided the evidence of the evolution of reson... |
| Databáze: | OpenAIRE |
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