Positron Emission Profiling Study of the Diffusion of 3-Methylpentane in Silicalite-1

Autor:	AM Arthur de Jong, Rutger A. van Santen, D Danny Schuring, AO Koriabkina
Rok vydání:	2003
Předmět:	Alkane chemistry.chemical_classification Chemistry Analytical chemistry General Chemistry Activation energy Partial pressure Thermal diffusivity Catalysis chemistry.chemical_compound Positron emission Zeolite 3-Methylpentane
Zdroj:	Topics in Catalysis. 24:103-113
ISSN:	1022-5528
DOI:	10.1023/b:toca.0000003082.55658.dd
Popis:	The influence of the loading on the self-diffusion of 3-methylpentane within silicalite-1 has been studied with Positron Emission Profiling technique. A monotonous decrease in the self-diffusivities of alkane was observed with zeolite loading, which could be approximated by a stretched exponential. As a consequence, the apparent activation energy increases with partial pressure.
Databáze:	OpenAIRE
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