A Doubly End-On Azido-Bridged Trinuclear Cu(II) Complex: Synthesis, Spectral and DFT Functional Studies

Autor:	Ching-Han Hu, Fu Xing Liao, Wen Yen Huang, Jui-Hsien Huang, Kuheli Das, Amitabha Datta
Rok vydání:	2011
Předmět:	chemistry.chemical_compound Crystallography Schiff base chemistry General Chemistry Functional studies
Zdroj:	Journal of Chemical Research. 35:140-143
ISSN:	2047-6507 1747-5198
DOI:	10.3184/174751911x12972790588178
Popis:	A trinuclear, doubly azido-bridged Cu(II) complex, [Cu1.50(L)(N3)3(CH3OH)]2, (LH = [(CH3)2NCH2CH2N=CHC6H3(OH) (OMe)]), has been synthesised and fully characterised by elemental analyses, IR, UV-Vis, EPR and DFT studies. Its single crystal X-ray structure reveals that adjacent CuII ions are linked by double end-on azido-bridges; thus the full molecule is generated by the site symmetry of a crystallographic two-fold rotation axis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ef225c26f63d87b22817d62cbd6d69ba https://doi.org/10.3184/174751911x12972790588178 Zobrazit plný text záznamu Plný text ve formátu PDF