Organic Catalysts for Photocontrolled Polymerizations
| Autor: | Brett P. Fors, Jacob T. Trotta |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Chemistry Radical Organic Chemistry Radical polymerization technology industry and agriculture Chain transfer macromolecular substances ROMP Polymer 010402 general chemistry Metathesis 01 natural sciences Combinatorial chemistry 0104 chemical sciences Catalysis Polymerization |
| Zdroj: | Synlett. 27:702-713 |
| ISSN: | 1437-2096 0936-5214 |
| DOI: | 10.1055/s-0035-1561264 |
| Popis: | Photocontrolled polymerization is an emerging field of study in which catalysis with organic-based dyes has enabled the practical and inexpensive synthesis of well-defined, spatially and temporally controlled polymeric structures. Herein, we review the current progress in the development of organic catalysts for photoregulated polymerizations. In particular, we highlight advances in metal-free variants of photomediated controlled radical polymerizations. In addition, we examine how the unique properties of these catalysts allow the development of two mechanistically distinct chain-growth polymerizations controlled by light. 1 Introduction 2 Photocontrolled Atom-Transfer Radical Polymerization (ATRP) 3 Photocontrolled Reversible Addition–Fragmentation Chain Transfer (RAFT) 4 Reversible Complexation-Mediated Polymerization (RCMP) 5 Photocontrolled Ring-Opening Metathesis Polymerization (ROMP) 6 Conclusion and Future Outlook |
| Databáze: | OpenAIRE |
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