| Popis: |
Experiments were performed to determine the results of carbonization under pressure of three coal liquefaction product (or by-product) materials and thus supply data needed as a design base for two concepts for advanced coal liquefaction plants. Solid-liquid separation underflow (SLSU) and solvent from a hydroextraction process were carbonized at 900/sup 0/F in an inert atmosphere at pressures up to 400 psig. Vacuum still bottoms from the H-Coal process were pyrolyzed at 1100/sup 0/F in a methane atmosphere at 400 psig. Results from carbonization of hydroextraction solvent and SLSU show that (1) only 1 to 7 percent of the solvent is degraded during carbonization at 900/sup 0/F and 400 psig, (2) the heavier fraction of the residue contributed the most toward coke formation, and (3) increased pressure increases the degree of coking of the heavier fractions. Results from pyrolysis of the vacuum still bottoms material at 1100/sup 0/F and 400 psig indicated that (1) small amounts of liquid are produced, (2) a significant quality of gas is produced, and (3) higher temperature will probably be required to produce free-flowing char. |
