The radiolytic reaction between graphite and CO2—III. Surface complexes

Autor:	F.S. Feates, J.R. Fryer
Rok vydání:	1971
Předmět:	Materials science Inorganic chemistry Oxide Sorption General Chemistry chemistry.chemical_compound chemistry Free surface Carbon dioxide Radiolysis General Materials Science Graphite Absorption (chemistry) Carbon monoxide
Zdroj:	Carbon. 9:511-516
ISSN:	0008-6223
DOI:	10.1016/0008-6223(71)90031-5
Popis:	Surface oxides form on graphite exposed to radiolysed CO2 at 425 K by a process which is first order with respect to sites available for sorption. The oxide is formed radiolytically and is at least partially decomposed on heating the graphite to 775 K. Oxide formation appears to be an essential preliminary to gasification since negligible gasification takes place from an oxide free surface. A mechanism is proposed for the oxidation of graphite by radiolysed CO2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eeb25446a0c03c84c4c3f391e3f533c2 https://doi.org/10.1016/0008-6223(71)90031-5