Accordion-like graphene by a facile and green synthesis method reinforcing polyolefin nanocomposites
| Autor: | Anping Huang, Junji Jia, Xiaojie Yan, Xie Kefeng, Yongxiao Bai, Wensheng Gao, Jiangong Li, Bochao Zhu |
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| Rok vydání: | 2017 |
| Předmět: |
Polypropylene
Nanocomposite Materials science Graphene General Chemical Engineering Graphite oxide 02 engineering and technology General Chemistry Polyethylene 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences law.invention Polyolefin Linear low-density polyethylene chemistry.chemical_compound chemistry law Ultimate tensile strength Polymer chemistry Composite material 0210 nano-technology |
| Zdroj: | RSC Advances. 7:31085-31092 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c7ra04139j |
| Popis: | Herein, accordion-like graphene with a large specific surface area, efficient reduction degree and designed functional groups was successfully synthesized via thermal expansion exfoliation of alkylated graphite oxide at relatively low temperature (below 170 °C) without any auxiliary equipment. This functional graphene (M-LTRGO) displayed an improved compatibility and interfacial interaction with polyolefin matrix. The graphene-reinforced polyolefin (including polypropylene and polyethylene) nanocomposites exhibited better mechanical strength and thermal stability than the neat and parallel graphene-reinforced polyolefin nanocomposites. The tensile breaking strength of random polypropylene (PPR) and linear low-density polyethylene (LLDPE) increased by 42.77% and 58.59%, respectively, after their incorporation at a loading amount of 0.5 wt%. Into M-LTRGO that is much more stronger than other graphene counterparts obtained via double screw melting compounding. This method provides a new route for the large-scale and green production of functional graphene, endowing the nanocomposites with various functional properties and enhanced mechanical performance, and may have great potential applications in structural engineering plastic and biomedical, soft protection, special packaging, and biotechnological areas. |
| Databáze: | OpenAIRE |
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