Dehydrochlorination of some naphthalene tetrachlorides and related compounds. Part III. Structure and dehydrochlorination of a 1,2,3,4-tetrachloro-1-phenyltetralin

Autor:	Hitomi Suzuki, G. W. Burton, Peter B. D. de la Mare, Keith R. Bedford
Rok vydání:	1974
Předmět:	Part iii chemistry.chemical_compound Chloroform Nitromethane Chemistry Aluminium Tetrachloride Chlorine chemistry.chemical_element Organic chemistry Carbon Medicinal chemistry Naphthalene
Zdroj:	Journal of the Chemical Society, Perkin Transactions 2. :459
ISSN:	1364-5471 0300-9580
DOI:	10.1039/p29740000459
Popis:	Chlorine reacts with 1-phenylnaphthalene in chloroform to give, among other products, a tetrachloride which has been characterised from its 1H n.m.r. spectrum as r-1,c-2,t-3,t-4-tetrachloro-1-phenyltetralin. On alkaline dehydrochlorination, it gives 2,3-dichloro-1-phenylnaphthalene almost exclusively; when heated in carbon disulphide or when treated in nitromethane with an excess of aluminium trichloride, it gives 2,4-dichloro-1-phenylnaphthalene and 2,3-dichloro-1-phenylnaphthalene in a ratio of ca. 2 : 1 or greater. The mechanistic implications of these results are discussed.
Databáze:	OpenAIRE
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