N,N,N′,N′,N″-Pentamethyl-N″-[(trifluorosilyl)methyl] phosphoric triamide. First example of the existence of intramolecular PO→Si coordination bond in the Si-containing phosphoric triamides

Autor:	Alexander I. Albanov, I. M. Lazarev, Nataliya F. Lazareva, V. A. Pestunovich
Rok vydání:	2007
Předmět:	Inorganic Chemistry Stereochemistry Chemistry Intramolecular force General Chemistry Medicinal chemistry
Zdroj:	Applied Organometallic Chemistry. 21:281-287
ISSN:	1099-0739 0268-2605
Popis:	The N,N,N′,N′,N″-pentamethyl-N″-(trifluorosilylmethyl)phosphoric triamide OP(NMe2)2N(Me) CH2SiF3 with intramolecular POSi coordination was formed by the reaction of N,N,N′,N′,N″-pentamethyl-N″[(triethoxysilyl)methyl]phosphoric triamide with BF3·Et2O. Copyright © 2007 John Wiley & Sons, Ltd.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ee74d5866218aa21a267cb482eeed5bb https://doi.org/10.1002/aoc.1174 Zobrazit plný text záznamu Plný text