ChemInform Abstract: ortho-Selective Nucleophilic Addition of Amines to 3-Borylbenzynes: Synthesis of Multisubstituted Anilines by the Triple Role of the Boryl Group

Autor:	Shigeaki Masuda, Kozumo Saito, Akira Takagi, Takashi Ikawa, Toyohiro Ito, Shuji Akai
Rok vydání:	2014
Předmět:	chemistry.chemical_compound Nucleophilic addition Trimethylsilyl Chemistry Group (periodic table) General Medicine Trifluoromethanesulfonate Medicinal chemistry Aryne
Zdroj:	ChemInform. 45
ISSN:	0931-7597
DOI:	10.1002/chin.201415074
Popis:	The investigations reveal that the nucleophilic addition to benzynes, generated in situ from triflate (I), exhibits higher ortho-selectivities than those of 3-(trimethylsilyl)benzynes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ee72f418fb71aa76cf9d7b1eff9c3dd7 https://doi.org/10.1002/chin.201415074 Zobrazit plný text záznamu Plný text