ChemInform Abstract: Ionic Liquids as Solvents for the Regioselective O-Alkylation of C/O Ambident Nucleophiles

Autor:	Jean-Jacques Brunet, Robert Perron, Meryam Badri
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Nucleophile Sodium Ionic liquid Polymer chemistry Halide Regioselectivity chemistry.chemical_element General Medicine Phosphonium Alkylation
Zdroj:	ChemInform. 23
ISSN:	0931-7597
DOI:	10.1002/chin.199252114
Popis:	The reaction of sodium β-naphthoxide with benzyl halides in molten tetraalkylammonium or phosphonium halides (at 110°C or below) leads to a highly regioselective O-alkylation. These new solvents, which can be quantitatively recovered at the end of the reaction, mimic the behaviour of dipolar aprotic solvents.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ee6cac4db04d53bcc5901d1c9b18b2b8 https://doi.org/10.1002/chin.199252114 Zobrazit plný text záznamu Plný text