Crystallographic studies of the structures of Au11(PPh3)7(SCN)3

Autor:	Marilyn M. Olmstead, Alan L. Balch, Xian B. Carroll, Christopher D. Lowe, Lucy M. C. Luong
Rok vydání:	2022
Předmět:	Thiocyanate Bent molecular geometry law.invention Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry law Halogen Materials Chemistry Cluster (physics) Molecule Physical and Theoretical Chemistry Crystallization
Zdroj:	Inorganica Chimica Acta. 530:120682
ISSN:	0020-1693
Popis:	The crystallization of two solvates of Au11(PPh3)7(SCN)3, 2Au11(PPh3)7(SCN)3·2C6H6·0.5EtOH (1) and Au11(PPh3)7(SCN)3·3EtOH (2), with (1) containing two independent molecules of the cluster, allows the positions of all of the ligands to finally be identified. Despite the bent nature of the thiocyanate ligands, they occupy similar sites to the ones that contain halogen ligands in Au11(PPh3)7Cl3, Au11(PPh3)7I3, and related molecules. However, the relative orientations of these thiocyanate ligands differ in the three cluster sites.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ee51e620850fc630ac9db45aec738cb7 https://doi.org/10.1016/j.ica.2021.120682 Zobrazit plný text záznamu Full Text from ScienceDirect