Influence de la complexation sur la réactivité de nitrates d'halogènes

Autor:	Didier Gaude, Raymond Le Goaller, Jean-Louis Pierre, Gisèle Gellon
Rok vydání:	1989
Předmět:	inorganic chemicals Bromine Chloroform Organic Chemistry chemistry.chemical_element Halogenation General Chemistry Medicinal chemistry Catalysis chemistry.chemical_compound chemistry Nitrate Nitration Pyridine Organic chemistry Halonium ion Triethylamine
Zdroj:	Canadian Journal of Chemistry. 67:104-108
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v89-018
Popis:	Iodine nitrate or bromine nitrate in acetonitrile or in chloroform react with a variety of phenolic substrates to form both halogenated and nitrated products. In the presence of strong complexing agents of halonium ions, no reaction occurs, while in the presence of pyridine or triethylamine, only halogenated phenols exhibiting a strong ortho-directing effect of the phenolic function are produced. Keywords: phenols, iodine nitrate, bromine nitrate, halogenation, nitration.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ee4df911e90909f0c8bb2e1ca06ace1d https://doi.org/10.1139/v89-018 Zobrazit plný text záznamu