Bimanes (1,5-diazabicyclo[3.3.0]octadienediones): Laser activity insyn-bimanes

Autor: Chun M. Lau, Kannappan Thangaraj, Govindarajulu Kumar, Vayalakkavoor T. Ramakrishnan, Edwin D. Stevens, Joseph H. Boyer, Ieva R. Politzer, Theodore G. Pavlopoulos
Rok vydání: 1990
Předmět:
Zdroj: Heteroatom Chemistry. 1:195-209
ISSN: 1098-1071
1042-7163
DOI: 10.1002/hc.520010302
Popis: The conversion of 3-methyl-4-benzyl-4-chloro-2-pyrazolin-5-one 10b was catalyzed by a mixture of potassium fluoride and alumina to give syn- (methyl,benzyl)bimane 6 (62%) without detectable formation of the anti isomer A6(a 1:1 mixture (87%) of the isomers 6 and A6 was obtained when the catalyst was potassium carbonate). (JG)
Databáze: OpenAIRE