Photocatalytic degradation of commercial dye, CI Reactive Red 35 in aqueous suspension: Degradation pathway and identification of intermediates by LC/MS

Autor:	Priti Bansal, Dhiraj Sud
Rok vydání:	2013
Předmět:	Decarboxylation Process Chemistry and Technology Reaction intermediate Ring (chemistry) Photochemistry Catalysis Hydroxylation chemistry.chemical_compound chemistry Degradation (geology) Reactive dye Physical and Theoretical Chemistry Photodegradation Bond cleavage
Zdroj:	Journal of Molecular Catalysis A: Chemical. :66-72
ISSN:	1381-1169
Popis:	The photodegradation of Reactive Red 35 dye by artificial UV light was investigated in the presence of titania P-25. Six reaction intermediates were identified and separated by LC/MS, giving insight into mechanistic details and degradation pathways. The degradation process takes place through competitive reactions such as removal of chromophoric group, hydroxylation of the aromatic ring, substitution on aromatic ring, devinylsulphonation, C N bond cleavage, decarboxylation and further ring opening to give aliphatic compounds. The probable degradation pathways were proposed and discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ee00235eb92650328c7bd17ebf8844b3 https://doi.org/10.1016/j.molcata.2013.03.018 Zobrazit plný text záznamu Full Text from ScienceDirect