Electron-excessive systems: Study of the character of spectral phenomena of weak magnetic fields and conformations of acetylenic amidoglycols

Autor:	M. Z. Zaripova, M. D. Isobaev, E. F. Venger, E. M. Glazunova
Rok vydání:	1992
Předmět:	Crystallography Rigidity (electromagnetism) Geminal Chemistry Stereochemistry Automotive Engineering General Chemistry Electronic structure Electron Spectral line Magnetic field
Zdroj:	Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1635-1640
ISSN:	1573-9171 1063-5211
Popis:	The synthesis was carried out of model acetylenic amidoglycols. Conclusions were made from an analysis of the PMR spectra on the possibility of transfer of magnetic fields through an electron-excessive acetylenic bond and on conformation of amidoglycols. The low value of the observed nonequivalency of the geminal methyl groups, separated from the asymmetric center by an acetylenic bond, in the PMR spectra is explained by characteristic features of the electronic structure and conformational rigidity of the acetylenic bond.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::edf59d42d04c70745ec33a57bb8830a7 https://doi.org/10.1007/bf00863585 Zobrazit plný text záznamu Full text from SpringerLink