Isolation and Characterization of the Molybdenum Alkylidyne Complex [(F3C)Me2CO]2Mo(C-t-Bu)[N(Ar)PC(H)(CMe2Ph)] and Its Conversion to a Phosphamolybdacyclobutene

Autor: Joseph W. Ziller, David R. Wheeler, Douglas A. Loy, Gregory M. Jamison, Randall S. Saunders, Todd M. Alam, Mark D. McClain
Rok vydání: 1996
Předmět:
Zdroj: Organometallics. 15:3244-3246
ISSN: 1520-6041
0276-7333
DOI: 10.1021/om960418z
Popis: Novel molybdenum alkylidyne [(F3C)Me2CO]2Mo(C-t-Bu)[N(Ar)PC(H)(CMe2Ph)] (Ar = 2,6-(i-Pr)2C6H3; 3b) is formed in the reaction of tert-butylphosphaalkyne 2 with molybdenum alkylidene 1b. Alkylidyne 3...
Databáze: OpenAIRE