Porous DMN-co-GMA copolymers modified with 1-(2-hydroxyethyl)-2-pyrrolidone
| Autor: | Magdalena Rogulska, Małgorzata Maciejewska |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Materials science
Scanning electron microscope 02 engineering and technology 021001 nanoscience & nanotechnology Condensed Matter Physics Methacrylate 01 natural sciences 010406 physical chemistry 0104 chemical sciences Thermogravimetry Differential scanning calorimetry Chemical engineering Specific surface area Copolymer Thermal stability Physical and Theoretical Chemistry Fourier transform infrared spectroscopy 0210 nano-technology |
| Zdroj: | Journal of Thermal Analysis and Calorimetry. 144:699-711 |
| ISSN: | 1588-2926 1388-6150 |
| DOI: | 10.1007/s10973-020-09496-z |
| Popis: | Porous microspheres obtained from 2,3-epoxypropyl methacrylate (GMA) and 1,4-di(methacryloyloxymethyl) naphthalene (DMN) were modified by the reaction of active oxirane group with 1-(2-hydroxyethyl)-2-pyrrolidone (HP). Spherical shape of the copolymers was confirmed by scanning electron microscopy whereas low-temperature nitrogen adsorption–desorption method was applied to determine their porous structure. It was found that the modification process did not change noticeably the internal structure of the materials. The specific surface area for both types of materials ranged from 41 to 106 m2g−1 depending on the molar ratio of the monomers. Changes, however, were observed in reference to thermal properties. They were studied using differential scanning calorimetry and thermogravimetry coupled with FTIR in inert and oxidative conditions. The reaction with HP reinforced thermal stability of the modified microspheres in helium atmosphere. Their initial decomposition temperatures (IDTs) increased to 273–281 °C. In air atmosphere, the values of IDTs were at the same level (248–269 °C). The modified beads decomposed in three (helium) or two (air) stages. |
| Databáze: | OpenAIRE |
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